The urethane rubber does have a shorter shelf life. It also deteriorates the more you use the mold, faster than silicone rubber. Urethanes tend to be a more advanced-user material too, so if this is your first venture into mold making, it may prove difficult to work with. In addition to this, even though they are "flexible", bending the mold off the product over and over (even just a few times) allows for the molecules to stretch and break, causing tiny tears pretty early in relation to silicone rubbers (silicones are specifically designed for a longer life over repeated flexing). I started on Urethane rubbers, and once I went to silicone, I was hitting myself for not trying it first.
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